Roger Federer (3), Suiza, vs. Xavier Malisse, Bélgica
Ana Ivanovic (14), Serbia, vs. Victoria Azarenka (2), Bielorrusia
Novak Djokovic (1), Serbia, vs. Viktor Troicki, Serbia

Cancha 1
Maria Sharapova (1), Rusia, vs. Sabine Lisicki (15), Alemania
Marin Cilic (16), Croacia, vs. Andy Murray (4), Gran Bretaña
David Ferrer (7), España, vs. Juan Martín del Potro (9), Argentina

Cancha 2
Serena Williams (6), EEUU, vs. Yaroslava Shvedova, Kazajstán
Agnieszka Radwanska (3), Polonia, vs. Camila Giorgi, Italia
Jo-Wilfried Tsonga (5), Francia, vs. Mardy Fish (10), EEUU

Cancha 3
Francesca Schiavone (24), Italia, vs. Petra Kvitova (4), República Checa
Kim Clijsters, Bélgica, vs. Angelique Kerber (8), Alemania
Richard Gasquet (18), Francia, vs. Florian Mayer (31), Alemania

Cancha 12
Tamira Paszek, Austria, vs. Roberta Vinci (21), Italia
Maria Kirilenko (17), Rusia, vs. Peng Shuai (30), China
Brian Baker, EEUU, vs. Philipp Kohlschreiber (27), Alemania